1386387-58-1

Basic information

• Product Name: (E)-1-(4'-N-acetylaminophenylsulfonyl)-2-phenylethene
• Synonyms: (E)-1-(4'-N-acetylaminophenylsulfonyl)-2-phenylethene
• CAS NO: 1386387-58-1
• Molecular Weight: 301.366
• Mol File: 1386387-58-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (E)-1-(4'-N-acetylaminophenylsulfonyl)-2-phenylethene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4'-N-acetylaminophenylsulfonyl)-2-phenylethene(1386387-58-1)
• EPA Substance Registry System: (E)-1-(4'-N-acetylaminophenylsulfonyl)-2-phenylethene(1386387-58-1)

Safety Data

• Hazardous Substances Data: 1386387-58-1(Hazardous Substances Data)

Upstream product

• 15898-43-8 sodium 4-acetamidobenzenesulfinate 
• 536-74-3 phenylacetylene 
• 6034-54-4 sodium p-acetaminobenzenesulfonate 
• 621-82-9 Cinnamic acid 
• 3989-50-2 4-acetamidobenzenesulfonylhydrazine 
• 140-10-3 (E)-3-phenylacrylic acid 
• 100-42-5 styrene 
• 1126-81-4 4-acetamidothiophenol 

Relevant articles and documents

Electrochemical Decarboxylative Sulfonylation of Cinnamic Acids with Aromatic Sulfonylhydrazides to Vinyl Sulfones

A stereoselective synthesis of (E)-vinyl sulfones has been developed via electrochemical oxidative N-S bond cleavage of aromatic sulfonylhydrazides, followed by cross-coupling reactions with cinnamic acids to form the C-S bond. The protocol proceeded smoo

Aerobic Copper-Catalyzed Synthesis of (E)-Vinyl Sulfones by Direct C-S Bond Oxidative Coupling

Copper-catalyzed aerobic oxidative C-S bond coupling reaction between thiophenols and aryl-substituted alkenes for (E)-vinyl sulfones synthesis is reported here. With air utilized as a green oxidant, this transformation not only produces various vinyl sulfones in moderate to good yields but also possesses a simple and ecofriendly system. To clarify the mechanism, kinetic experiments has been investigated.

Aerobic copper-catalyzed synthesis of (E)-alkenyl sulfones and (E)-β-halo-alkenyl sulfones via addition of sodium sulfinates to alkynes

Copper-catalyzed sulfonylation of alkynes using sodium sulfinates in air produced regio- and stereoselectively (E)-alkenyl sulfones. When a CuCl catalyst was employed, the hydrosulfonylation proceeded syn-selectively, and (E)-alkenyl sulfones were synthesized in excellent yields. In contrast, the reaction using CuI catalyst produced (E)-β-haloalkenyl sulfones anti-selectively in the presence of potassium halides. Furthermore, the (E)-β-bromoalkenyl sulfones are possible to convert into various alkenyl sulfones by Suzuki-Miyaura coupling.