138649-96-4

Basic information

• Product Name: (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one
• Synonyms: (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one
• CAS NO: 138649-96-4
• Molecular Weight: 439.576
• Mol File: 138649-96-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one(138649-96-4)
• EPA Substance Registry System: (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one(138649-96-4)

Safety Data

• Hazardous Substances Data: 138649-96-4(Hazardous Substances Data)

Upstream product

• 131685-53-5 (S)-4-benzyl-3-propionyl-2-oxazolidinone 
• 115205-40-8 1-phenylsulfanylcyclopentane carboxaldehyde 

Downstream Products

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 138751-07-2 (1S,2S)-2-methyl-1-(1-phenylsulfanylcyclopentyl)propane-1,3-diol 
• 138649-99-7 (1R,2S)-3-Amino-2-methyl-1-(1-phenylsulfanyl-cyclopentyl)-propan-1-ol 
• 138649-99-7 (2S,3S)-3-hydroxy-2-methyl-3-(1-phenylsulfanylcyclopentyl)propylamine 
• 138649-98-6 (2R,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclopentyl)-propionamide 
• 138649-98-6 (2S,3S)-3-hydroxy-2-methyl-3-(1-phenylsulfanylcyclopentyl)propanamide 
• 138650-00-7 (2S,3S)-3-hydroxy-2-methyl-3-(1-phenylsulfanylcyclopentyl)propyl-N-tosylamide 
• 138649-95-3 (3R,4R)-3-methyl-4-phenylsulfanyl-1-tosyl-1-azaspiro<4.4>nonane 
• 138751-05-0 (3R,4R)-3-methyl-4-phenylsulfanyl-1-oxa-spiro<4.4>nonane 

Relevant articles and documents

Asymmetric synthesis of spirocyclic pyrrolidines and tetrahydrofurans by chiral aldol reactions and phenylthio migration

Highly enantioselective aldol reactions of the boron enolate of (S)-N-propionyl-4-(phenylmethyl)-2-oxazolidinone with α-phenylthio cycloalkanecarbaldehydes were achieved. Cyclisation of the chiral phenylthiosulphonamide and diols gave the title compounds in excellent yields and enantiomeric excess.