138715-77-2

Basic information

• Product Name: phenyl-λ³-iodanediyl dicyclohexanecarboxylate
• Synonyms: phenyl-λ³-iodanediyl dicyclohexanecarboxylate
• CAS NO: 138715-77-2
• Molecular Weight: 458.336
• Mol File: 138715-77-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenyl-λ³-iodanediyl dicyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl-λ³-iodanediyl dicyclohexanecarboxylate(138715-77-2)
• EPA Substance Registry System: phenyl-λ³-iodanediyl dicyclohexanecarboxylate(138715-77-2)

Safety Data

• Hazardous Substances Data: 138715-77-2(Hazardous Substances Data)

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 98-89-5 Cyclohexanecarboxylic acid 

Downstream Products

• 56947-80-9 2-cyclohexyl-4-methylquinoline 
• 137655-83-5 methyl 2-cyclohexylisonicotinate 
• 1441636-02-7 3-(cyclohexylmethyl)-1,3-dimethylindolin-2-one 
• 18326-94-8 2,6-dicyclohexyl-4-methylpyridine 
• 15787-48-1 2-cyclohexyl-4-methylpyridine 
• 1613289-93-2 6-cyclohexyl-2-fluorophenanthridine 
• 123325-08-6 diethyl 2-(cyclohexyl)ethylphosphonate 
• 126002-58-2 1-(2-cyclohexylethylsulfonyl)benzene 

Relevant articles and documents

A benzene-bridged divanadium complex-early transition metal catalyst for alkene alkylarylation with PhI(O2CR)2viadecarboxylation

The synthesis, structure and catalytic activity of a benzene-bridged divanadium complex were comprehensively studied. The reduction of (Nacnac)VCl2(1) (Nacnac = (2,6-iPr2C6H3NCMe)2HC) supported by β-diketiminate with potassium graphite (KC8) by employing benzene as the solvent allows access to the benzene-bridged inverted-sandwich divanadium complex (μ-η6:η6-C6H6)[V(Nacnac)]2(2a), which can catalyze alkene alkylarylation with hypervalent iodine(iii) reagents (HIRs)viadecarboxylation to generate regioselectively diverse indolinones. Furthermore, the mild nature of this reaction was amenable to a wide range of functionalities on alkenes and HIRs. Mechanistic studies revealed a relay sequence of decarboxylative radical alkylation/radical arylation/oxidative re-aromatization.

Direct β-C(sp3)-H Acetoxylation of Aliphatic Carboxylic Acids

The controlled construction of defined oxidation patterns is one of the key aspects in the synthesis of natural products and bioactive molecules. Towards this goal, we herein report a novel protocol for the Pd-catalyzed direct β-C(sp3)-H acetoxylation of aliphatic carboxylic acids. The protocol enables the use of free carboxylic acids in one step and without the need of introducing specialized strong directing groups. In our studies, we found that the use of a "traceless base" was crucial for the development of a synthetically useful transformation. Furthermore, the synthetic utility of the products obtained was demonstrated by their use in subsequent transformations.