138835-73-1

Basic information

• Product Name: (2S)-dimethyl 2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)malate
• Synonyms: (2S)-dimethyl 2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)malate
• CAS NO: 138835-73-1
• Molecular Weight: 684.783
• Mol File: 138835-73-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-dimethyl 2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)malate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-dimethyl 2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)malate(138835-73-1)
• EPA Substance Registry System: (2S)-dimethyl 2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)malate(138835-73-1)

Safety Data

• Hazardous Substances Data: 138835-73-1(Hazardous Substances Data)

Upstream product

• 617-55-0 dimethyl (S)-malate 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 

Relevant articles and documents

Stereochemistry of the macrolactins

The macrolactins are a group of six 24-membered ring lactones isolated from a taxonomically-undefinable deep sea bacterium. Macrolactin A, the parent aglycone, shows a number of interesting biological activities, including the protection of T-lympboblast cells against human HIV viral replication. Herein we report the stereochemistries of macrolactin B and macrolactin F, which were determined by a combination of 13C-acetonide analysis using isotopically enriched acetone, oxidative degradation, and chemical correlation. Macrolactins B and F were found to have the same stereochemistry at each of the common stereogenic centers, and so we expect that macrolactin A, the aglycone of macrolactin B, has the stereochemistry 7S,13S,15R,23R.