138904-01-5

Basic information

• Product Name: 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl 2-pyridinecarboxylate
• CAS NO: 138904-01-5
• Molecular Weight: 645.752
• Mol File: 138904-01-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl 2-pyridinecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl 2-pyridinecarboxylate(138904-01-5)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl 2-pyridinecarboxylate(138904-01-5)

Safety Data

• Hazardous Substances Data: 138904-01-5(Hazardous Substances Data)

Upstream product

• 29745-44-6 pyridine-2-carbonyl chloride 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 98-98-6 2-Picolinic acid 

Downstream Products

• 55094-26-3 methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1-6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 56632-57-6 methyl O-2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyll-α-D-glucopyranoside 
• 77117-44-3 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 64694-18-4 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 41736-89-4 3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)cholesterol 
• 70753-59-2 O-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl]cholesterol 
• 67525-69-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(tert-butoxy)tetrahydro-2H-pyran 
• 78153-80-7 tert-butyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 132097-74-6 (2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran 
• 132097-74-6 (2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)tetrahydro-2H-pyran 

Relevant articles and documents

Synthesis of Glycosyl Chlorides and Bromides by Chelation Assisted Activation of Picolinic Esters under Mild Neutral Conditions

A general method has been developed for the formation of glycosyl chlorides and bromides from picolinic esters under mild and neutral conditions. Benchtop stable picolinic esters are activated by a copper(II) halide species to afford the corresponding products in high yields with a traceless leaving group. Rare β glycosyl chlorides are accessible via this route through neighboring group participation. Additionally, glycosyl chlorides with labile protecting groups previously not easily accessible can be prepared.