1389253-30-8

Basic information

• Product Name: 5-hydroxy-1-allyl-5-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)pyrrolidin-2-one
• CAS NO: 1389253-30-8
• Molecular Weight: 349.349
• Mol File: 1389253-30-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-hydroxy-1-allyl-5-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)pyrrolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-hydroxy-1-allyl-5-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)pyrrolidin-2-one(1389253-30-8)
• EPA Substance Registry System: 5-hydroxy-1-allyl-5-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)pyrrolidin-2-one(1389253-30-8)

Safety Data

• Hazardous Substances Data: 1389253-30-8(Hazardous Substances Data)

Upstream product

• 2555-14-8 N-allylsuccinimide 
• 1000293-91-3 trimethyl(1,1,2,2-tetrafluoro-2-(phenylsulfanyl)ethyl)silane 

Relevant articles and documents

Application of PhSCF2CF2SiMe3 as a tandem anion and radical tetrafluoroethylene equivalent: Fluoride-catalyzed addition to N-substituted cyclic imides followed by radical cyclization

PhSCF2CF2SiMe3 undergoes a fluoride-catalyzed nucleophilic addition to N-substituted cyclic amides affording adducts in moderate to good yields. Reductive cleavage of the phenylsulfanyl group of N-methylated adducts under radical conditions yields the corresponding tetrafluoroethyl-containing adducts in excellent yields. Under the same reduction conditions, N-allylated adducts undergo 6-exo radical cyclization to afford the corresponding tetrafluorinated 1-azabicyclic compounds in moderate to good yields and cis selectivities. Georg Thieme Verlag Stuttgart · New York.