138996-22-2Relevant articles and documents
Novel reaction of 1-aryl-2-bromodiazene 1-oxides with olefins. Synthesis of 1-aryl-2-(2-bromoalkyl)diazene 1-oxides
Churakov, A. M.,Tyurin, A. Yu.,Goncharova, E. L.,Ioffe, S. L.,Strelenko, Yu. A.,Tartakovsky, V. A.
, p. 890 - 896 (2007/10/02)
The addition of 1-aryl-2-bromodiazene 1-oxides to olefins yields 1-aryl-2-(2-bromoalkyl)diazene 1-oxides (4).A radical mechanism of the reaction has been suggested.Compounds 4 decompose to give bromohydrazones of formaldehyde and aldehydes.The structural factors that affect the rate of this process are discussed.