13901-82-1

Basic information

• Product Name: dimethyl 2,5-dimethyl-1-phenyl-pyrrole-3,4-dicarboxylate
• Synonyms: dimethyl 2,5-dimethyl-1-phenyl-pyrrole-3,4-dicarboxylate
• CAS NO: 13901-82-1
• Molecular Formula: C₁₆H₁₇NO₄
• Molecular Weight: 0
• Mol File: 13901-82-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 384.2°Cat760mmHg
• Flash Point: 186.2°C
• Appearance: /
• Density: 1.15g/cm³
• Vapor Pressure: 4.15E-06mmHg at 25°C
• Refractive Index: 1.548
• CAS DataBase Reference: dimethyl 2,5-dimethyl-1-phenyl-pyrrole-3,4-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2,5-dimethyl-1-phenyl-pyrrole-3,4-dicarboxylate(13901-82-1)
• EPA Substance Registry System: dimethyl 2,5-dimethyl-1-phenyl-pyrrole-3,4-dicarboxylate(13901-82-1)

Safety Data

• Hazardous Substances Data: 13901-82-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H17NO4/c1-10-13(15(18)20-3)14(16(19)21-4)11(2)17(10)12-8-6-5-7-9-12/h5-9H,1-4H3

Upstream product

• 28750-70-1 2-acetoanilinopropionic acid 
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• 27126-76-7 [hydroxy(tosyloxy)iodo]benzene 
• 74536-45-1 2,3-diacetyl succinic acid dimethyl ester 
• 62-53-3 aniline 

Relevant articles and documents

Catalytic redox-neutral C-H functionalisation with TEMPO in water to access aminomethyl-substituted pyrroles

A redox-neutral C-H functionalisation in water employing catalytic TEMPO to synthesize aminomethyl-substituted pyrroles is reported. Starting from cheap and commercial chemical feedstocks (ketoesters and anilines), our approach delivered targeted products in good yields and represents an endeavour to address redox economy in radical transformations.

THE USE OF N-ETHYL-N'-DIMETHYLAMINOPROPYLCARBODIIMIDE OR SILICON TETRACHLORIDE IN PYRROLE SYNTHESES.

Two methods are used for mesoionic oxazolone formation in the synthesis of pyrroles in 1,3-dipolar cycloaddition reactions.N-ethyl-N'-dimethylaminopropylcarbodiimide or silicon tetrachloride are used to activate the N-acylamino acid.