1391837-97-0

Basic information

• Product Name: 1-(1,1'-bicyclopropyl-1-yl)-3-pentylbenzene
• Synonyms: 1-(1,1'-bicyclopropyl-1-yl)-3-pentylbenzene
• CAS NO: 1391837-97-0
• Molecular Weight: 228.378
• Mol File: 1391837-97-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(1,1'-bicyclopropyl-1-yl)-3-pentylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,1'-bicyclopropyl-1-yl)-3-pentylbenzene(1391837-97-0)
• EPA Substance Registry System: 1-(1,1'-bicyclopropyl-1-yl)-3-pentylbenzene(1391837-97-0)

Safety Data

• Hazardous Substances Data: 1391837-97-0(Hazardous Substances Data)

Upstream product

• 56700-77-7 (E,Z)-1,3-nonadiene 
• 1391837-72-1 (1-cyclopropylcyclopropyl)ethyne 

Relevant articles and documents

Diels-Alder reactions for the construction of cyclopropylarenes

The straightforward synthesis of new bicyclopropyl-substituted alkynes and 1,3-dienes and their application in cobalt-catalyzed Diels-Alder reactions are described. The cycloaddition processes generated the desired bicyclopropyl-substituted arene derivatives in moderate to good yields, depending on the steric congestion of the reaction partners. The regioselectivity of the cycloaddition was controlled by the ligand coordinated to the cobalt center. The cyclopropyl moiety remained unchanged over the course of the Diels-Alder reaction, indicating that no radical type intermediates were formed. Only in a single case did the DDQ oxidation of the primarily formed dihydroaromatic product lead to ring opening of a cyclopropyl subunit. In all of the other cases, cyclopropyl-modified arenes with various functionalities were obtained. Copyright