139192-50-0

Basic information

• Product Name: Benzenesulfonamide, N-[1-(hydroxymethyl)-2-methylpropyl]-2,4,6-trimethyl-, (S)-
• CAS NO: 139192-50-0
• Molecular Formula: C14H23NO3S
• Molecular Weight: 285.408
• Mol File: 139192-50-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-[1-(hydroxymethyl)-2-methylpropyl]-2,4,6-trimethyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-[1-(hydroxymethyl)-2-methylpropyl]-2,4,6-trimethyl-, (S)-(139192-50-0)
• EPA Substance Registry System: Benzenesulfonamide, N-[1-(hydroxymethyl)-2-methylpropyl]-2,4,6-trimethyl-, (S)-(139192-50-0)

Safety Data

• Hazardous Substances Data: 139192-50-0(Hazardous Substances Data)

Upstream product

• 130892-94-3 (S)-3-Methyl-2-(2,4,6-trimethyl-benzenesulfonylamino)-butyric acid 
• 773-64-8 2-mesitylenesulphonyl chloride 
• 2026-48-4 (S)-valinol 

Downstream Products

• 1032477-24-9 2,2'-diacetoxy-3,3'-bis[(2S,4S)-4-(2-methylethyl)-3-(2,4,6-trimethylbenzenesulfonyl)-1,3-oxazolidinyl]-biphenyl 
• 1032477-14-7 2,2'-diacetoxy-5,5'-di-tert-butyl-3,3'-bis[(2S,4S)-4-(2-methylethyl)-3-(2,4,6-trimethylbenzenesulfonyl)-1,3-oxazolidinyl]biphenyl 
• 187532-09-8 (3S,4S)-5-methyl-4-[N-(2,4,6-trimethylbenzenesulfonyl)amino]-1-hexen-3-ol 
• 187532-10-1 (3R,4S)-5-methyl-4-[N-(2,4,6-trimethylbenzenesulfonyl)amino]-1-hexen-3-ol 
• 220306-83-2 Methanesulfonic acid (E)-(S)-5-methyl-4-(2,4,6-trimethyl-benzenesulfonylamino)-hex-2-enyl ester 
• 220306-79-6 Carbonic acid methyl ester (E)-(S)-5-methyl-4-(2,4,6-trimethyl-benzenesulfonylamino)-hex-2-enyl ester 
• 220306-75-2 N-((E)-(S)-4-Hydroxy-1-isopropyl-but-2-enyl)-2,4,6-trimethyl-benzenesulfonamide 
• 220306-69-4 (E)-(S)-5-Methyl-4-(2,4,6-trimethyl-benzenesulfonylamino)-hex-2-enoic acid methyl ester 
• 187532-12-3 (2S,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine 
• 187532-11-2 (2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine 
• 253675-93-3 Methyl (4S,2E)-2-bromo-5-methyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-enoate 
• 220324-12-9 (4S,2Z)-2-Bromo-O-methylsulfonyl-5-methyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-en-1-ol 
• 220324-04-9 Methyl (4S,2Z)-2-bromo-5-methyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-enoate 
• 220324-08-3 (4S,2Z)-2-Bromo-5-methyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hex-2-en-1-ol 

Relevant articles and documents

Efficient synthesis of new chiral 1,2-benzothiazin-3-one 1,1-dioxide derivatives via lateral lithiation of 3-N-mesitylenesulfonyl-1,3-oxazolidin-2-ones

Chiral 3-N-mesitylenesulfonyl-1,3-oxazolidin-2-ones 4a-e derived from (l)- and (d)-amino acids 1a-e undergo lateral lithiation with lithium diisopropylamide and TMEDA in anhydrous THF to provide new optically-active 1,2-benzothiazin-3-one 1,1-dioxide deri

A Thermodynamic Preference of Chiral N-Methanesulfonyl and N-Arenesulfonyl 2,3-cis-3-Alkyl-2-Vinylaziridines over Their 2,3-Trans-Isomers: Useful Palladium(0)-Catalyzed Equilibration Reactions for the Synthesis of (E)-Alkene Dipeptide Isosteres

Palladium(0)-catalyzed reactions of N-methanesulfonyl- or N-(arenesulfonyl)-3-alkyl-2-vinylaziridines reveal that 2,3-cis-isomers are more stable than the corresponding 2,3-trans-isomers in accord with ab initio calculations. A highly stereoselective synthetic route to (E)-alkene dipeptide isosteres having desired stereochemistries from 2,3-cis-3-isobutyl-2-vinylaziridine by the use of organocopper chemistry is also presented.