1391930-82-7

Basic information

• Product Name: 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolidin-1-yl]pyridine
• Synonyms: 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolidin-1-yl]pyridine
• CAS NO: 1391930-82-7
• Molecular Weight: 274.171
• Mol File: 1391930-82-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolidin-1-yl]pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolidin-1-yl]pyridine(1391930-82-7)
• EPA Substance Registry System: 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolidin-1-yl]pyridine(1391930-82-7)

Safety Data

• Hazardous Substances Data: 1391930-82-7(Hazardous Substances Data)

Upstream product

• 54660-06-9 2-pyrrolidinopyridine 
• 73183-34-3 bis(pinacol)diborane 

Relevant articles and documents

Rh-catalyzed borylation of N-adjacent C(sp3)-H bonds with a silica-supported triarylphosphine ligand

Direct C(sp3)-H borylation of amides, ureas, and 2-aminopyridine derivatives at the position α to the N atom, which gives the corresponding α-aminoalkylboronates, has been achieved with a heterogeneous catalyst system consisting of [Rh(OMe)(cod)]2 and a silica-supported triarylphosphine ligand (Silica-TRIP) that features an immobilized triptycene-type cage structure with a bridgehead P atom. The reaction occurs not only at terminal C-H bonds but also at internal secondary C-H bonds under mild reaction conditions (25-100 °C, 0.1-0.5 mol % Rh).