1392115-07-9

Basic information

• Product Name: (R)-(-)-methyl 2-((4-methyl-2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)(phenyl)methyl)acrylate
• Synonyms: (R)-(-)-methyl 2-((4-methyl-2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)(phenyl)methyl)acrylate
• CAS NO: 1392115-07-9
• Molecular Weight: 361.397
• Mol File: 1392115-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(-)-methyl 2-((4-methyl-2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)(phenyl)methyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-methyl 2-((4-methyl-2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)(phenyl)methyl)acrylate(1392115-07-9)
• EPA Substance Registry System: (R)-(-)-methyl 2-((4-methyl-2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)(phenyl)methyl)acrylate(1392115-07-9)

Safety Data

• Hazardous Substances Data: 1392115-07-9(Hazardous Substances Data)

Upstream product

• 956833-12-8 methyl 2-{[(tert-butoxycarbonyl)oxy](phenyl)methyl}acrylate 
• 34105-39-0 N-phenylitaconimide 

Relevant articles and documents

Direct asymmetric allylic alkenylation of N-itaconimides with Morita-Baylis-Hillman carbonates

The asymmetric allylic alkenylation of Morita-Baylis-Hillman (MBH) carbonates with N-itaconimides as nucleophiles has been developed using a commercially available Cinchona alkaloid catalyst. A variety of multifunctional chiral α-methylene-β-maleimide esters were attained in moderate to excellent yields (up to 99%) and good to excellent enantioselectivities (up to 91% ee). The origin of the regio- and stereoselectivity was verified by DFT methods. Calculated geometries and relative energies of various transition states strongly support the observed regio- and enantioselectivity.