139277-16-0

Basic information

• Product Name: (1R,2S,4S,5R,6S)-6-Hydroxy-5-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid
• Synonyms: (1R,2S,4S,5R,6S)-6-Hydroxy-5-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid
• CAS NO: 139277-16-0
• Molecular Weight: 266.318
• Mol File: 139277-16-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,4S,5R,6S)-6-Hydroxy-5-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,4S,5R,6S)-6-Hydroxy-5-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid(139277-16-0)
• EPA Substance Registry System: (1R,2S,4S,5R,6S)-6-Hydroxy-5-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid(139277-16-0)

Safety Data

• Hazardous Substances Data: 139277-16-0(Hazardous Substances Data)

Upstream product

• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 135735-95-4 (1S,2S,3S,4R,5R)-3-Benzyloxy-5-benzyloxymethyl-cyclohexane-1,2,4-triol 
• 139277-11-5 (1R,2R,3R,4S,5S)-2-Benzenesulfonyl-3-benzyloxy-5-benzyloxymethyl-7-oxa-bicyclo[2.2.1]heptane 
• 139277-13-7 (1S,2R,6S)-3-Benzenesulfonyl-2-benzyloxy-6-benzyloxymethyl-cyclohex-3-enol 
• 139277-10-4 (1S,2S,3S,4R,5R)-2-Benzenesulfonyl-3-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-7-oxa-bicyclo[2.2.1]heptane 
• 139277-12-6 (1S,2R,6S)-3-Benzenesulfonyl-2-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-3-enol 
• 139277-18-2 (1S,2S,3S,4R,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane 
• 139277-14-8 (4aS,8R,8aS)-7-Benzenesulfonyl-8-benzyloxy-4a,5,8,8a-tetrahydro-4H-benzo[1,3]dioxine 
• 139277-19-3 (1S,2S,3S,4R,5R)-3-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane 
• 139277-17-1 (4aR,6S,7S,8R,8aR)-8-Benzyloxy-hexahydro-benzo[1,3]dioxine-6,7-diol 
• 139277-15-9 (4aR,8R,8aR)-8-Benzyloxy-4a,5,8,8a-tetrahydro-4H-benzo[1,3]dioxine 
• 10226-73-0 DL-(1,2,4/3,5)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 139277-09-1 (1R,2S,3R,4S,6R)-6-Hydroxymethyl-3-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptan-2-ol 

Relevant articles and documents

Strain-Directed Bridge Cleavage of (Phenylsulfonyl)-7-oxabicycloheptane Derivatives: Application to the Total Synthesis of Carba-α-DL-glucopyranose

New methodology to prepare highly oxygenated cyclohexenylsulfones by regioselective β-elimination of (phenylsulfonyl)-7-oxabicycloheptane derivatives has been developed, and its application to the total synthesis of carba-α-DL-glucopyranose is desc