139370-99-3

Basic information

• Product Name: Benzene, 1-methoxy-4-[[2-(phenylsulfinyl)-2-propenyl]oxy]-
• CAS NO: 139370-99-3
• Molecular Formula: C16H16O3S
• Molecular Weight: 288.367
• Mol File: 139370-99-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[[2-(phenylsulfinyl)-2-propenyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[[2-(phenylsulfinyl)-2-propenyl]oxy]-(139370-99-3)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[[2-(phenylsulfinyl)-2-propenyl]oxy]-(139370-99-3)

Safety Data

• Hazardous Substances Data: 139370-99-3(Hazardous Substances Data)

Upstream product

• 17061-86-8 1-methoxy-4-(2-propynyloxy)benzene 
• 74338-75-3 2-cyanoethyl(phenyl)sulfoxide 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 139371-03-2 4-methoxy-2-(2-phenylsulfinyl-2-propenyl)phenol 

Relevant articles and documents

The Claisen Rearrangement of 2-Phenylsulfinyl-2-propenyl Phenyl Ethers - A New Route to Functionalized Phenols and 2-Methylbenzofurans

The hitherto unknown Claisen rearrangement of 2-phenylsulfinyl-2-propenyl phenyl ethers to the corresponding 2-(2-phenylsulfinyl-2-propenyl)phenols is reported.The latter compounds underwent Michael reactions with a variety of nucleophiles to provide functionalized phenolic adducts.O-Alkylation of the initial rearrangement products with 3-bromo-2-phenylsulfinyl-1-propene and 2,3-dibromo-1-propene followed by sigmatropic rearrangement provided a promising route to 7-substituted 2-methylbenzofurans.