139622-45-0

Basic information

• Product Name: methyl (4,5)-anti-4-(3',4'-dimethoxyphenyl)-5-hydroxy-2(E)-hexenoate
• CAS NO: 139622-45-0
• Molecular Weight: 280.321
• Mol File: 139622-45-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl (4,5)-anti-4-(3',4'-dimethoxyphenyl)-5-hydroxy-2(E)-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (4,5)-anti-4-(3',4'-dimethoxyphenyl)-5-hydroxy-2(E)-hexenoate(139622-45-0)
• EPA Substance Registry System: methyl (4,5)-anti-4-(3',4'-dimethoxyphenyl)-5-hydroxy-2(E)-hexenoate(139622-45-0)

Safety Data

• Hazardous Substances Data: 139622-45-0(Hazardous Substances Data)

Upstream product

• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 91-16-7 1,2-dimethoxybenzene 
• 14202-27-8 (+/-) methyl (4,5)-trans-epoxy-(2E)-hexenoate 

Downstream Products

• 148906-73-4 C₁₇H₂₂O₆ 

Relevant articles and documents

Facile preparation of methyl 5-aryl-4-hydroxyhex-2(E)-enoate, chiral synthon of bisabolane-type sesquiterpenes, based on lipase-catalyzed kinetic resolution and rearrangement of an aryl group

The lipase-catalyzed enantioselective acetylation of racemic methyl (4S*,5S*)-4-aryl-5-hydroxyhex-2(E)-enoates 1a-h was performed and efficient resolutions were achieved (E >400) by using CAL-B. After brosylation of the obtained opti

A facile chemoenzymatic route to optically active 4,5-disubstituted-2E-hexenoate derivatives. I

The reaction of (±) methyl 4,5-trans-epoxy-2E-hexenoate (2) with aromatic nucleophiles having an electron-donating group in the presence of BF3 · Et2O gave the 4,5-anti-5-hydroxy-4- or/and 2,5-anti-5-hydroxy-2-substituted products. T