1396319-24-6

Basic information

• Product Name: dimethyl (((4-methylphenyl)sulfonamido)(4-(trifluoromethyl)phenyl)methyl)phosphonate
• Synonyms: dimethyl (((4-methylphenyl)sulfonamido)(4-(trifluoromethyl)phenyl)methyl)phosphonate
• CAS NO: 1396319-24-6
• Molecular Weight: 437.377
• Mol File: 1396319-24-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dimethyl (((4-methylphenyl)sulfonamido)(4-(trifluoromethyl)phenyl)methyl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl (((4-methylphenyl)sulfonamido)(4-(trifluoromethyl)phenyl)methyl)phosphonate(1396319-24-6)
• EPA Substance Registry System: dimethyl (((4-methylphenyl)sulfonamido)(4-(trifluoromethyl)phenyl)methyl)phosphonate(1396319-24-6)

Safety Data

• Hazardous Substances Data: 1396319-24-6(Hazardous Substances Data)

Upstream product

• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 96-36-6 methyl phosphite 
• 198012-02-1 4-methyl-N-(4-trifluoromethylbenzylidene)-benzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 36198-87-5 dimethyl trimethylsilyl phosphite 

Relevant articles and documents

Enantioselective Aza-Reformatsky Reaction with Ketimines

Here, an enantioselective aza-Reformatsky reaction using acyclic ketimine substrates is presented. Using α-phosphorated ketimines as electrophilic substrates and a simple BINOL-derived ligand, phosphorated analogues of aspartic acid holding chiral tetrasubstituted carbons are efficiently obtained with excellent enantioselectivity through an asymmetric organocatalytic Reformatsky-type reaction. The phosphorated analogues of aspartic acid have been used for the synthesis of phosphorus-containing enantiopure tetrasubstituted β-lactams.