1396518-01-6

Basic information

• Product Name: tert-butyl cyclohexyl(4-methoxybenzyl)carbamate
• Synonyms: tert-butyl cyclohexyl(4-methoxybenzyl)carbamate
• CAS NO: 1396518-01-6
• Molecular Weight: 319.444
• Mol File: 1396518-01-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-butyl cyclohexyl(4-methoxybenzyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl cyclohexyl(4-methoxybenzyl)carbamate(1396518-01-6)
• EPA Substance Registry System: tert-butyl cyclohexyl(4-methoxybenzyl)carbamate(1396518-01-6)

Safety Data

• Hazardous Substances Data: 1396518-01-6(Hazardous Substances Data)

Upstream product

• 623-12-1 4-chloromethoxybenzene 
• 1397275-19-2 potassium tert-butyl cyclohexyl{(trifluoroborato)methyl}carbamate 
• 3712-40-1 tert-butyl cyclohexylcarbamate 
• 1396514-87-6 tert-butyl cyclohexyl{(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl}carbamate 
• 100-60-7 N-methylcyclohexylamine 
• 34619-03-9 tert-butyldicarbonate 
• 104-92-7 1-bromo-4-methoxy-benzene 

Relevant articles and documents

Ligand-controlled α- And β-arylation of acyclic N-boc amines

The palladium-catalyzed ligand-controlled arylation of α-zincated acyclic amines, obtained by directed α-lithiation and transmetalation, is described. Whereas PtBu3 gave rise to α-arylated Boc-protected amines, more flexible N-phenylazole-based phosphine ligands induced major β-arylation through migrative cross-coupling. All manner of control: The arylation of α-zincated acyclic Boc-protected amines was selectively performed at the α- or β-position in a ligand-controlled manner. α-Arylation occurs by direct reductive elimination of the α-palladated intermediate whereas β-arylation involves palladium migration along the alkyl chain. Boc=tert-butoxycarbonyl.