1396629-21-2Relevant articles and documents
Fe-Catalyzed Direct α C-H Amination of Carbonyl Compounds
Murru, Siva,Lott, Charles Seth,Fronczek, Frank R.,Srivastava, Radhey S.
, p. 2122 - 2125 (2015)
A direct Fe-catalyzed α-amination of 1,3-dicarbonyl compounds has been accomplished using arylhydroxylamines as aminating agents. This novel protocol allows convenient access to α-amino carbonyl derivatives without the need for any postreaction manipulations. This is an operationally simple procedure that works at low temperatures in shorter reaction times and produces high yields with excellent N-selectivity. (Figure Presented).
Synthesis of enantiomerically enriched 3-amino-2-oxindoles through a palladium-mediated asymmetric intramolecular arylation of α-ketimino amides
Tolstoy, Paeivi,Lee, Samantha X. Y.,Sparr, Christof,Ley, Steven V.
supporting information, p. 4810 - 4813,4 (2012/12/12)
A highly efficient and enantioselective synthesis of 3-amino-2-oxindoles through a palladium-catalyzed asymmetric intramolecular arylation of R-ketimino amides using (R)-DiFluorPhos as the coordinating ligand is reported. This report constitutes the first
