13985-43-8Relevant articles and documents
Nitro-group-directed selective deacylation and desulfonation
Ji, Xiujie,Li, Chunbao
, p. 2478 - 2482 (2008/02/04)
Nitro-substituted phenolic esters and sulfonates were successfully and selectively deacylated and desulfonated, respectively. The directing effect of the nitro group is supported by the excellent regioselectivities and good yields. These reactions demonst
The intrinsic photoferroelectric effect in the smectic C* phase of a chiral azobenzene
Saipa, Alexander,Osipov, Mikhail A.,Lanham, Kenneth W.,Chang, Catherine H.,Walba, David M.,Giesselmann, Frank
, p. 4170 - 4177 (2008/02/04)
The ferroelectric properties in the liquid-crystalline smectic C* phase of the chiral mesogenic azobenzene (S)-4-(4-decyloxy-phenylazo)benzoic acid 4-(1-methylhexyloxy)-3-nitro-phenyl ester ('W470') were studied and found to be strongly dependent on the i
Preparation of a novel cross-linked polymer for second-order nonlinear optics
Trolls?s, Mikael,Orrenius, Christian,Sahlén, Fredrik,Gedde, Ulf W.,Norin, Torbj?rn,Hult, Anders,Hermann, David,Rudquist, Per,Komitov, Lachezar,Lagerwall, Sven T.,Lindstr?m, Jan
, p. 8542 - 8548 (2007/10/03)
A novel cross-linked pyroelectric polymer with pronounced second-order nonlinear optical properties has been prepared. A multistep synthesis with several selective transformations including a kinetic resolution (transesterification) with the highly enantioselective Candida antarctica lipase B, yielded the monomer 4''-{(R)-(-)-2[(10-acryloyloxy)decyl]oxy}-3-nitrophenyl 4-{4'-[(11-acryloyloxy)undecyloxy]phenyl}benzoate A2c which displayed a ferroelectric chiral smectic C phase with large spontaneous polarization (175 nC/cm2). The monomer was poled and subsequently cross-linked by in-situ photopolymerization in the surface-stabilized ferroelectric liquid crystalline state. The cross-linked pyroelectric polymer exhibited an electro-optical coefficient (r22-r12) of 15-35 pm/V.