1398508-07-0

Basic information

• Product Name: dimethyl 2‐{(S)‐(2‐nitrophenyl)[(1S)‐2‐oxocyclohexyl]methyl}propanedioate
• Synonyms: dimethyl 2‐{(S)‐(2‐nitrophenyl)[(1S)‐2‐oxocyclohexyl]methyl}propanedioate
• CAS NO: 1398508-07-0
• Molecular Weight: 363.367
• Mol File: 1398508-07-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: dimethyl 2‐{(S)‐(2‐nitrophenyl)[(1S)‐2‐oxocyclohexyl]methyl}propanedioate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2‐{(S)‐(2‐nitrophenyl)[(1S)‐2‐oxocyclohexyl]methyl}propanedioate(1398508-07-0)
• EPA Substance Registry System: dimethyl 2‐{(S)‐(2‐nitrophenyl)[(1S)‐2‐oxocyclohexyl]methyl}propanedioate(1398508-07-0)

Safety Data

• Hazardous Substances Data: 1398508-07-0(Hazardous Substances Data)

Upstream product

• 65974-52-9 dimethyl 2-[(2-nitrophenyl)methylidene]malonate 
• 108-94-1 cyclohexanone 
• 552-89-6 2-nitro-benzaldehyde 
• 108-59-8 malonic acid dimethyl ester 

Relevant articles and documents

Stereoselective conjugate addition of ketones to alkylidene malonates using thiourea-sulfonamide organocatalyst

In this study, stereoselective conjugate addition of ketones to alkylidene malonates using organocatalyst has been developed. The reaction in the presence of 20?mol% of a novel thiourea-sulfonamide organocatalyst afforded conjugate adducts in moderate to

Highly enantioselective michael addition of ketone to alkylidene malonates catalyzed by binaphthyl sulfonimides in water

Binaphthyl sulfonimides have been developed to catalyze the asymmetric Michael addition of ketone to alkylidene malonates, affording the corresponding Michael products in good to high yields (up to 98%) with good to excellent diastereoselectivity (up to 9

Highly enantioselective conjugate addition of ketones to alkylidene malonates catalyzed by a pyrrolidinyl-camphor-derived organocatalyst

Pyrrolidinyl-camphor derivatives have been proven to be efficient organocatalysts for enantioselective conjugate addition of ketones to alkylidene malonates, affording high chemical yields (up to 95 %) of the corresponding products with high to excellent levels of diastereoselectivity (up to >99:1 dr) and enantioselectivity (up to 96%ee) under solvent-free reaction conditions at ambient temperature.