1399049-71-8Relevant articles and documents
Control of reactivity of phosphine imides by intramolecular coordination with an organoboryl group
Kano, Naokazu,Yanaizumi, Kazuhide,Meng, Xiangtai,Kawashima, Takayuki
, p. 429 - 434 (2012/11/07)
Phosphine imides with a boryl substituent 3-5 were synthesized. Their structures were revealed to have a tetracoordinated boron and a phosphorus atom, featuring the N-B coordination by X-ray crystallographic analysis and NMR spectroscopy. The phosphine imide moiety was persistent to hydrolysis, methylation, and the aza-Wittig reaction. The N-B coordination remained intact upon treating with pyridine or fluoride ion. Copyright