139976-68-4Relevant articles and documents
First Evidence of Unhindered Silanimines Obtained by Flash Vacuum Thermolysis and Vacuum Gas-Solid Reaction
Denis, Jean-Marc,Guenot, Pierre,Letulle, Marguerite,Pellerin, Bruno,Ripoll, Jean-Louis
, p. 1397 - 1400 (2007/10/02)
The unhindered silanimines 1,1-dimethyl-N-phenylsilanimine (2) and N-isopropyl-1,1-dimethylsilanimine (10) have been generated by flash vacuum thermolysis of the N-allylsilanamine 1 and vacuum gas-solid reaction of the 1-chlorosilanamine 9, respectively.The silanimines 2 and 10 have been characterized by MS as well as by chemical trapping to yield 3 or dimerization to the cyclodisilazane 11.Key Words: Flash vacuum thermolysis / Retro-ene reaction / Silanamine / Silanimine / Vacuum gas solid reaction