1400999-68-9Relevant articles and documents
Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions
Egami, Hiromichi,Shimizu, Ryo,Sodeoka, Mikiko
supporting information, p. 5503 - 5506 (2012/11/07)
Oxytrifluoromethylation reaction of styrene derivatives and alkynes with external and internal oxygen nucleophiles, catalyzed by copper (I) salts under mild conditions, was developed. Direct formation of a β- trifluoromethylstyrene derivative from a styrene derivative was also achieved by the reaction in the presence of a Bronsted acid. Further transformation of the oxytrifluoromethylated products was conducted to demonstrate their utility. 2012 Elsevier Ltd. All rights reserved.