1402238-83-8Relevant articles and documents
Anti -Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(III) reagents
Chen, Hui,Kaga, Atsushi,Chiba, Shunsuke
, p. 5481 - 5485 (2016)
anti-Selective aminofluorination of alkenes with amidines was enabled by hypervalent iodine(iii) reagents, affording 4-fluoroalkyl-2-imidazolines. Further reductive ring-opening of the 2-imidazoline moiety could deliver highly functionalized 3-fluoropropane-1,2-diamine derivatives.
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc) 2
Sanjaya, Stephen,Chiba, Shunsuke
supporting information, p. 5342 - 5345 (2013/01/15)
A Cu-catalyzed aminoacetoxylation of N-alkenylamidines has been achieved using PhI(OAc)2 as an oxygen source for synthesis of 4-acetoxymethyl-4,5-dihydroimidazoles, which could be further converted into 2,3-diaminopropanol derivatives using AlH