1402551-70-5

Basic information

• Product Name: [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2
• Synonyms: [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2
• CAS NO: 1402551-70-5
• Molecular Weight: 733.907
• Mol File: 1402551-70-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2(1402551-70-5)
• EPA Substance Registry System: [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2(1402551-70-5)

Safety Data

• Hazardous Substances Data: 1402551-70-5(Hazardous Substances Data)

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 106-45-6 para-thiocresol 

Downstream Products

• 620-94-0 di-(p-tolyl)sulfane 
• 4279-70-3 (2?methylphenyl)(4?methylphenyl) sulfide 
• 127567-55-9 4-methylphenyl 1-naphthyl sulfide 
• 1402551-76-1 C₁₆H₁₆OS 

Relevant articles and documents

Synthesis of copper(I) thiolate complexes in the thioetherification of aryl halides

The copper(I) thiophenolato complexes 1-3 containing 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline (Me2phen) were isolated in excellent yields from reactions of [CuOtBu]4 with the dative ligands and subsequent addition of 1 equiv of arenethiol. These complexes were characterized spectroscopically and crystallographically. X-ray structural analysis of a single crystal of [(phen)Cu(μ-SC6H 5)]2 (1) revealed that this complex adopts a neutral dimeric form with a weak Cu-Cu bonding interaction. These complexes were found to react with iodoarenes to form aryl sulfide products. The intermediacy of such complexes in copper-catalyzed thioetherification of aryl halides was demonstrated by the reactivity with p-tolyl iodide and o-tolyl iodide to form two aryl thioethers with selectivities similar to those of catalytic reactions conducted with the same two iodoarenes.