1402831-16-6Relevant articles and documents
Highly efficient synthesis of unsymmetrical 1,3-diynes from organoalane reagents and alkynyl bromides mediated by a nickel catalyst
Mo, Song,Shao, Xue-Bei,Zhang, Gang,Li, Qing-Han
, p. 27243 - 27247 (2017)
Highly efficient and simple cross-coupling reactions of alkynylbromides with organoalane reagents for the synthesis of unsymmetrical 1,3-diynes derivatives using Ni(OAc)2 (2-5 mol%)/(o-furyl)3P (4-10 mol%) as a catalyst are reported. Excellent yields (up to 94%) were obtained for a wide range of substrates at rt or 60 °C for 2-3 h in Et2O or toluene.
Enaminone ligand-assisted homo- and cross-coupling of terminal alkynes under mild conditions
Liu, Yunyun,Wang, Chunping,Wang, Xiaobo,Wan, Jie-Ping
, p. 3953 - 3955 (2013/07/25)
Copper-catalyzed oxidative coupling reactions of terminal alkynes have been performed at room temperature by using enaminone as effective ligand. Both symmetrical and unsymmetrical 1,3-diynes bearing various functional groups have been synthesized in mode