14034-57-2

Basic information

• Product Name: anilinium p-tolylsulphonate
• Synonyms: anilinium p-tolylsulphonate;Aniline p-toluenesulfonate;Benzenamine, 4-methylbenzenesulfonate;Benzenamine, 4-methylbenzenesulfonate (1:1);Einecs 237-870-8
• CAS NO: 14034-57-2
• Molecular Formula: C₆H₇N*C₇H₈O₃S
• Molecular Weight: 265.3281
• EINECS: 237-870-8
• Mol File: 14034-57-2.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 484.8°Cat760mmHg
• Flash Point: 247°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 3.27E-10mmHg at 25°C
• CAS DataBase Reference: anilinium p-tolylsulphonate(CAS DataBase Reference)
• NIST Chemistry Reference: anilinium p-tolylsulphonate(14034-57-2)
• EPA Substance Registry System: anilinium p-tolylsulphonate(14034-57-2)

Safety Data

• Hazardous Substances Data: 14034-57-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H8O3S.C6H7N/c1-6-2-4-7(5-3-6)11(8,9)10;7-6-4-2-1-3-5-6/h2-5H,1H3,(H,8,9,10);1-5H,7H2

Upstream product

• 222851-56-1 N-phenylsulfinylamine 
• 68-34-8 phenyl toluenesulfonamide 
• 17783-69-6 indan-2-yl p-toluenesulphonate 
• 62-53-3 aniline 
• 2346-07-8 neopentyl tosylate 
• 14135-71-8 1-phenyl-2-propyl-4-toluenesulfonate 
• 87813-97-6 Toluene-4-sulfonic acid 1,3-dioxo-1,3,3a,4,7,7a-hexahydro-isoindol-2-yl ester 
• 75057-16-8 N-(p-Tolylsulphonyloxy)-1-phenylnaphthalene-2,3-dicarboximide 
• 80-48-8 methyl p-toluene sulfonate 
• 80-40-0 ethyl ester of p-toluenesulfonic acid 
• 154416-00-9 Toluene-4-sulfonic acid 1-methyl-1-phenyl-ethyl ester 
• 6165-76-0 propargyl p-toluenesulfonate 
• 13295-53-9 cyclobutylmethyl 4-methylbenzenesulfonate 
• 3725-11-9 cyclohexylmethyl p-toluenesulfonate 

Downstream Products

• 106273-53-4 benzenediazonium 4-methylbenzenesulfonate 
• 100820-44-8 (3aRS,4RS,9bRS)-4-phenyl-2,3,3a,4,5,9b-hexahydrofuro[3,2-c]quinoline 
• 100820-44-8 4-phenyl-2,3,3a,4,5,9b-hexahydrofuran[3,2-c]quinoline 

Relevant articles and documents

Sulphanilic acid as a recyclable bifunctional organocatalyst in the selective conversion of lignocellulosic biomass to 5-HMF

We herein report an unprecedented integrated process using organic salts as bifunctional organocatalysts under absolutely metal-free conditions for the conversion of a wide range of biomass-derived carbohydrates, cellulose, and even untreated lignocellulose (e.g. straw and barley husk) into 5-hydroxymethylfurfural (5-HMF) in a well-known water/MIBK biphasic solvent system.

Rhodium(I)-catalyzed synthesis of aryltriethoxysilanes from arenediazonium tosylate salts with triethoxysilane

An efficient method for the preparation of aryltriethoxy-silanes from arenediazonium tosylate salts has been developed, which expands the substrates of rhodium-catalyzed silylation from iodides, bromides, and triflates to diazonium salts. A new method for hydrodediazoniation has also been explored.

KINETICS AND MECHANISM OF AMINOLYSIS OF PROPARGYL AND 1-METHYL-PROPARGYL ARENESULPHONATES

Kinetic studies were carried out on the aminolysis of propargyl and 1-methylpropargyl arenesulphonates in acetonitrile at 45.0 deg C.The cross-interaction constants, ρxz and βxz, are similar to, but smaller than, those for the SN2 processes at other primary and secondary carbon centers.Compared with the allyl series, the smaller magnitude of ρxz and βxz reflects a looser transition state, which in turn leads to a lower rate despite the greater Taft's ?* value and the lower intrinsic (ΔE0) and thermodynamic barriers (ΔE0).