14040-79-0

Basic information

• Product Name: N¹, N²-diphenethyloxalamide
• Synonyms: N¹, N²-diphenethyloxalamide
• CAS NO: 14040-79-0
• Molecular Weight: 296.369
• Mol File: 14040-79-0.mol
• Article Data: 9

Chemical Properties

• Melting Point: 86 °C
• Density: 1.136±0.06 g/cm3(Predicted)
• CAS DataBase Reference: N¹, N²-diphenethyloxalamide(CAS DataBase Reference)
• NIST Chemistry Reference: N¹, N²-diphenethyloxalamide(14040-79-0)
• EPA Substance Registry System: N¹, N²-diphenethyloxalamide(14040-79-0)

Safety Data

• Hazardous Substances Data: 14040-79-0(Hazardous Substances Data)

Upstream product

• 64-04-0 phenethylamine 
• 78-83-1 2-methyl-propan-1-ol 
• 81682-58-8 Oxalic acid N-(2-phenylethyl)monoamide 
• 107-21-1 ethylene glycol 
• 79-37-8 oxalyl dichloride 
• 49837-58-3 2-methoxy-5-morpholino-1,3-oxazole-4-carbonitrile 
• 20172-98-9 N-Phenethyl-oxalamic acid methyl ester 
• 3659-97-0 1-methylparabanic acid 
• 95-92-1 oxalic acid diethyl ester 
• 144-62-7 oxalic acid 

Downstream Products

• 64-04-0 phenethylamine 
• 84500-68-5 1,1'-bi(1,2,3,4-dihydroisoquinolyl) 

Relevant articles and documents

Novel chiral C1-1′,2′,3′,4′-tetrahydro-1,1′- bisisoquinolines: synthesis, resolution, and applications in catalytic enantioselective reactions

A straightforward synthesis of a structurally constrained C1-1′,2′,3′,4′-tetrahydro-1,1′- bisisoquinoline 1 is described. Resolution of this compound has been achieved successfully. The preparation of chiral N-alkyl, urea, and thiourea derivati

Urethanes synthesis from oxamic acids under electrochemical conditions

Urethane synthesis via oxidative decarboxylation of oxamic acids under mild electrochemical conditions is reported. This simple phosgene-free route to urethanes involves an in situ generation of isocyanates by anodic oxidation of oxamic acids in an alcoholic medium. The reaction is applicable to a wide range of oxamic acids, including chiral ones, and alcohols furnishing the desired urethanes in a one-pot process without the use of a chemical oxidant.

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

A robust and practical protocol for preparing alkyl aryl ethers has been developed, which relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero)aryl halides. The reaction scope is very general for a variety of coupling partners, particularly for challenging secondary alcohols and (hetero)aryl chlorides. In case of coupling with aryl chlorides and bromides, two oxalic diamides serve as the powerful ligands. The tert-butoxide is first demonstrated as a ligand for Cu-catalyzed coupling reaction, leading to alkoxylation of aryl iodides complete at room temperature. Additionally, a number of carbohydrate derivatives are applicable for this coupling reaction, affording the corresponding carbohydrate-aryl ethers in 29-98% yields.