1404380-69-3

Basic information

• Product Name: cyclobutylmethyl phenyl selenide
• Synonyms: cyclobutylmethyl phenyl selenide
• CAS NO: 1404380-69-3
• Molecular Weight: 225.192
• Mol File: 1404380-69-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cyclobutylmethyl phenyl selenide(CAS DataBase Reference)
• NIST Chemistry Reference: cyclobutylmethyl phenyl selenide(1404380-69-3)
• EPA Substance Registry System: cyclobutylmethyl phenyl selenide(1404380-69-3)

Safety Data

• Hazardous Substances Data: 1404380-69-3(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 16408-62-1 cyclobutylmethyl iodide 
• 17247-58-4 (Bromomethyl)cyclobutane 

Relevant articles and documents

Corey-Chaykovsky Cyclopropanation of Nitronaphthalenes: Access to Benzonorcaradienes and Related Systems

Nitronaphthalene derivatives react as Michael acceptors in the Corey-Chaykovsky reaction with alkyl phenyl selenones and alkyl diphenyl sulfonium salts. Mechanistic studies reveal that sterically demanding substituents at the carbanionic center favor formation of cyclopropanes and suppress competitive β-elimination to the alkylated products. The transformation, demonstrated also on heterocyclic nitroquinoline and nitroindazolines, is an example of transition metal-free dearomatization method.