14073-00-8

Basic information

• Product Name: 3-METHYL-4-NITROQUINOLINE N-OXIDE
• Synonyms: 3-METHYL-4-NITROQUINOLINE N-OXIDE;3-methyl-4-nitroquinoline 1-oxide;3-methyl-4-nitro-1-oxidoquinolin-1-ium
• CAS NO: 14073-00-8
• Molecular Formula: C10H8N2O3
• Molecular Weight: 204.18212
• Mol File: 14073-00-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 342.67°C (rough estimate)
• Flash Point: 189.4°C
• Appearance: /
• Density: 1.3244 (rough estimate)
• Vapor Pressure: 6.32E-06mmHg at 25°C
• Refractive Index: 1.5910 (estimate)
• CAS DataBase Reference: 3-METHYL-4-NITROQUINOLINE N-OXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHYL-4-NITROQUINOLINE N-OXIDE(14073-00-8)
• EPA Substance Registry System: 3-METHYL-4-NITROQUINOLINE N-OXIDE(14073-00-8)

Safety Data

• Hazardous Substances Data: 14073-00-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H8N2O3/c1-7-6-11(13)9-5-3-2-4-8(9)10(7)12(14)15/h2-6H,1H3

Upstream product

• 1873-55-8 3-methylquinoline N-oxide 
• 612-58-8 3-methylquinoline 

Downstream Products

• 19701-33-8 4-amino-3-methyl quinoline 

Relevant articles and documents

Visible-Light-Mediated Enantioselective Photoreactions of 3-Alkylquinolones with 4- O-Tethered Alkenes and Allenes

The title compounds undergo intramolecular [2 + 2] photocycloaddition reactions when irradiated with visible light in the presence of a chiral sensitizer. Up to four defined stereogenic centers are formed in a single step (14 examples with a tethered alkene, 6 examples with an allene, 72-99percent yield, 81-99percent ee) at catalyst loadings as low as 0.5 mol percent. The alkyl group in the 3-position is crucial for the success of the reaction as it leads to a significant decrease of the triplet energy.