1407999-33-0

Basic information

• Product Name: C₂₁H₂₄N₂O₆
• Synonyms: C₂₁H₂₄N₂O₆
• CAS NO: 1407999-33-0
• Molecular Weight: 400.431
• Mol File: 1407999-33-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₁H₂₄N₂O₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₁H₂₄N₂O₆(1407999-33-0)
• EPA Substance Registry System: C₂₁H₂₄N₂O₆(1407999-33-0)

Safety Data

• Hazardous Substances Data: 1407999-33-0(Hazardous Substances Data)

Upstream product

• 94-47-3 2-Phenylethyl benzoate 
• 1972-28-7 diethylazodicarboxylate 

Relevant articles and documents

Radical amination of C(sp3)-H bonds using N -hydroxyphthalimide and dialkyl azodicarboxylate

A direct conversion of C(sp3)-H bonds to C(sp3)-N bonds has been achieved by utilizing catalytic N-hydroxyphthalimide (NHPI) and stoichiometric dialkyl azodicarboxylate. NHPI functions as a precursor of the electron-deficient phthalimide N-oxyl radical (PINO) to abstract hydrogens, and dialkyl azodicarboxylate acts as a trapping agent of the resultant carbon radical to generate the hydrazine derivatives. This C-H amination proceeds in a highly chemoselective manner with a wide applicability to functionalize benzylic, propargylic, and aliphatic C-H bonds. Furthermore, the obtained hydrazine compounds were readily converted to the corresponding carbamates or amines. Hence, the present protocol for direct introduction of the nitrogen functionality serves as a powerful tool for efficient construction of nitrogen-substituted natural products and pharmaceuticals.