1408280-75-0

Basic information

• Product Name: dimethyl 4-(benzo[d][1,3]dioxol-5-yl)-6-methylisophthalate
• Synonyms: dimethyl 4-(benzo[d][1,3]dioxol-5-yl)-6-methylisophthalate
• CAS NO: 1408280-75-0
• Molecular Weight: 328.321
• Mol File: 1408280-75-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl 4-(benzo[d][1,3]dioxol-5-yl)-6-methylisophthalate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 4-(benzo[d][1,3]dioxol-5-yl)-6-methylisophthalate(1408280-75-0)
• EPA Substance Registry System: dimethyl 4-(benzo[d][1,3]dioxol-5-yl)-6-methylisophthalate(1408280-75-0)

Safety Data

• Hazardous Substances Data: 1408280-75-0(Hazardous Substances Data)

Upstream product

• 5164-76-1 dimethyl glutaconate 
• 3160-37-0 4-(benzo[d][1,3]dioxol-5-yl)but-3-en-2-one 

Relevant articles and documents

Base-catalyzed efficient tandem [3 + 3] and [3 + 2 + 1] annulation-aerobic oxidative benzannulations

An efficient synthesis of substituted benzenes via a base-catalyzed [3 + 3] aerobic oxidative aromatization of α,β-unsaturated carbonyl compounds with dimethyl glutaconate was reported. All the reactions were carried out under mild, metal-free conditions to afford the products in high to excellent yields with molecular oxygen as the sole oxidant and water as the sole byproduct. Furthermore, a more convenient tandem [3 + 2 + 1] aerobic oxidative aromatization reaction was developed through the in situ generation of the α,β-unsaturated carbonyl compounds from aldehydes and ketones.