141033-73-0

Basic information

• Product Name: Cyclohexene, 4-(1-methylethenyl)-1-[(methylthio)methyl]-, (S)-
• CAS NO: 141033-73-0
• Molecular Formula: C11H18S
• Molecular Weight: 182.33
• Mol File: 141033-73-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 4-(1-methylethenyl)-1-[(methylthio)methyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 4-(1-methylethenyl)-1-[(methylthio)methyl]-, (S)-(141033-73-0)
• EPA Substance Registry System: Cyclohexene, 4-(1-methylethenyl)-1-[(methylthio)methyl]-, (S)-(141033-73-0)

Safety Data

• Hazardous Substances Data: 141033-73-0(Hazardous Substances Data)

Upstream product

• 93040-77-8 Dithiocarbonic acid O-(4-isopropenyl-cyclohex-1-enylmethyl) ester S-methyl ester 
• 536-59-4 perillol 
• 74940-37-7 S-methyl S-isocarveyl dithiocarbonate 
• 624-92-0 Dimethyldisulphide 
• 536-59-4 (-)-perillyl alcohol 

Downstream Products

• 141033-74-1 (4S)-7-(methylsulfinyl)-p-mentha-1,8-diene 

Relevant articles and documents

Investigations Concerning an Unexpected Reaction between the Dimsyl Anion (= (Methylsulfinyl)methanide) and a γ,δ-Epoxy-ketone

The reaction of 2,2-dimethyl-5-(1,2-epoxypropyl)cyclohexanone (7) with t-BuOK, in DMSO furnished a small amount of 5-(1-hydroxyprop-2-enyl)-2,2-dimethylcyclohexanone (12) and the 4 unexpected products 13-16 which contain one to three additional C-atoms (Scheme 2).The relative configuration of the major product 1-(4',4'-dimethyl-2',3'-dimethylidenecyclohexyl)propane-1,2-diol (15) was shown to be 1RS,2RS, 1'SR via NOE measurements performed on a derivative thereof.A crossover experiment in DMSO/DMSO 1:1 as solvent showed that the two additional C-atoms of this product originate from a single molecule of DMSO (Scheme 5).A tentative mechanistic scheme, consistent with all experimental observations, is proposed which involves a -sigmatropic corroborated part of this hypothetic scheme by taking recourse to a model compound (7-(methylsulfinyl)-p-mentha-1,8-diene (32/33), readily prepared in two steps from perilla alcohol (39)), which reacted as predicted by the proposed mechanism (Schemes 9 and 10).