141081-71-2

Basic information

• Product Name: 2-Propenoic acid, 3-(2,2-dimethyl-1,3-dioxan-5-yl)-, ethyl ester
• CAS NO: 141081-71-2
• Molecular Formula: C11H18O4
• Molecular Weight: 214.262
• Mol File: 141081-71-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(2,2-dimethyl-1,3-dioxan-5-yl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2,2-dimethyl-1,3-dioxan-5-yl)-, ethyl ester(141081-71-2)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2,2-dimethyl-1,3-dioxan-5-yl)-, ethyl ester(141081-71-2)

Safety Data

• Hazardous Substances Data: 141081-71-2(Hazardous Substances Data)

Upstream product

• 4728-12-5 2,2-dimethyl-5-hydroxymethyl-1,3-dioxane 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 141081-81-4 ((R)-Toluene-4-sulfinyl)-acetic acid (S)-4-oxo-2-(toluene-4-sulfonyloxymethyl)-butyl ester 
• 141081-78-9 (3S,Rs)-<3,4-dihydro-6-(p-tolylsulfinyl)methyl-2H-pyran-3-yl>methyl p-toluenesulfonate 
• 141081-83-6 (3R,Rs)-3-<(p-tolylsulfinyl)acetoxymethyl>butan-4-olide 
• 141081-82-5 (3S,Rs)-3-<(p-tolylsulfinyl)acetoxymethyl>butan-4-olide 
• 141081-72-3 (Rs)-2,2-dimethyl-5-<3-oxo-4-(p-tolylsulfinyl)butyl>-1,3-dioxane 
• 141081-73-4 1-((R)-Toluene-4-sulfinylmethyl)-2,6-dioxa-bicyclo[2.2.2]octane 

Relevant articles and documents

Facile synthesis of (±)-paeonilide

(Chemical Equation Presented) (±)-Paeonilide, a novel monoterpenoid metabolite from the roots of Paeonia delavayi showing anti-platelet activating factor activity, is convergently synthesized in five steps with 59% overall yield. The application of benzoyl peroxide-promoted radical addition of unsaturated ester to aldehyde and subsequent topologically favored cyclization greatly simplified the synthesis.

Asymmetric Fuctionalisation of Prochiral 1,3-Diols Based on an Efficient 1,6-Chiral Induction: the Diastereoselective C-O Bond Fission in Chiral β-Arylsulfinyl Acetal via Two Types of Chelation Control

The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C-O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).