141100-75-6

Basic information

• Product Name: (2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-butyltetrahydro-2H-pyran
• CAS NO: 141100-75-6
• Molecular Weight: 580.764
• Mol File: 141100-75-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-butyltetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-butyltetrahydro-2H-pyran(141100-75-6)
• EPA Substance Registry System: (2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-butyltetrahydro-2H-pyran(141100-75-6)

Safety Data

• Hazardous Substances Data: 141100-75-6(Hazardous Substances Data)

Upstream product

• 4196-35-4 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide 
• 1116-70-7 tri(n-butyl)aluminium 
• 1193390-86-1 (2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-(1,1-bis(phenylsulfonyl)butyl)tetrahydro-2H-pyran 
• 109-72-8 n-butyllithium 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 

Downstream Products

• 261955-94-6 (2S,3S,4R,5S)-3,4,5-Tris-benzyloxy-2-butyl-6-methylene-tetrahydro-pyran 
• 891783-18-9 (2S,3S,4R,5S,6S)-3,4,5-Tris-benzyloxy-2-butyl-6-iodomethyl-tetrahydro-pyran 
• 891783-17-8 ((2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-6-butyl-tetrahydro-pyran-2-yl)-methanol 

Relevant articles and documents

A Mitsunobu route to C-glycosides

C-Glycosides were successfully prepared via dehydrative alkylation under Mitsunobu conditions, using substituted sulfonyl methanes as nucleophiles. The materials prepared were converted to useful C-glycoside intermediates. An application of this approach

SYNTHESIS OF C-GLUCOPYRANOSIDES ON THE BASIS OF THE REACTION OF ORGANOALUMINUM COMPOUNDS WITH A 2,3,4,6-TETRA-O-BENZYL-α-D-GLUCOPYRANOSIDE

The reaction of 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide with organoaluminum compounds containing various radicals leads to C-glucopyranosides in ca. 40-80 percent yields.High stereoselectivity of the reaction (α:β = 90:10) is observed when trial