141212-06-8

Basic information

• Product Name: (R)-2-(4-tert-Butyl-phenyl)-1-((R)-toluene-4-sulfinyl)-propan-2-ol
• CAS NO: 141212-06-8
• Molecular Weight: 330.491
• Mol File: 141212-06-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(4-tert-Butyl-phenyl)-1-((R)-toluene-4-sulfinyl)-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(4-tert-Butyl-phenyl)-1-((R)-toluene-4-sulfinyl)-propan-2-ol(141212-06-8)
• EPA Substance Registry System: (R)-2-(4-tert-Butyl-phenyl)-1-((R)-toluene-4-sulfinyl)-propan-2-ol(141212-06-8)

Safety Data

• Hazardous Substances Data: 141212-06-8(Hazardous Substances Data)

Upstream product

• 943-27-1 4'-t-butylacetophenone 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 

Relevant articles and documents

Substituent Effect on the Enantioface-Differentiating Reaction of (R)- with m- or p-Substituted Acetophenones

When lithiomethyl p-tolyl sulfoxide derived from (R)-(+)- was allowed to react with acetophenones which have a variety of m- or p-substituents, the corresponding diastereomeric mixture of β-hydroxy sulfoxides (RSSC and RSRC) was produced.The degree of enantioselectivity was affected by the nature of the substituent on benzene ring.The logarithms of RSSC/RSRC values thus obtained gave a good correlation with Hammett's ? values, affording a negative straight line.The results have been discussed in view of the stereochemical course of the reaction.