141245-03-6Relevant articles and documents
Synthesis of (+/-)-Isopiperitenol by Fluoride Ion Mediated Cyclization of Allylsilane Moiety Incorporated in Terpene Aldehydes
Nakamura, Hideshi,Oya, Toyohisa,Murai, Akio
, p. 929 - 931 (1992)
Fluoride ion mediated cyclization of aldehydes (1 and 2) having regioisomeric allylsilane functionalities gave a mixture of cis- and trans-isopiperitenol (3).The aldehydes (1) reacted faster and showed better stereoselectivity than the regioisomeric aldeh