141250-03-5Relevant articles and documents
Synthesis of 4-Epoxy-4-C-methyleneglycosylceramides, Potential Glycosyltransferase Inhibitors
Plewe, Michael,Sandhoff, Konrad,Schmidt, Richard R.
, p. 699 - 708 (2007/10/02)
D-Glucose was transformed into the 4-deoxy-4-C-methylene derivative 1.Dihydroxylation of 1 and then selective O-tosylation afforded 4-C-(tosyloxymethyl)glucoside 3.Subsequent hydrogenolytic O-debenzylation, selective O-acetylation, treatment with a base,