141375-87-3

Basic information

• Product Name: Benzenemethanol, a-(1-ethenylidenepentyl)-a-methyl-
• CAS NO: 141375-87-3
• Molecular Formula: C15H20O
• Molecular Weight: 216.323
• Mol File: 141375-87-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-ethenylidenepentyl)-a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-ethenylidenepentyl)-a-methyl-(141375-87-3)
• EPA Substance Registry System: Benzenemethanol, a-(1-ethenylidenepentyl)-a-methyl-(141375-87-3)

Safety Data

• Hazardous Substances Data: 141375-87-3(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 100859-51-6 1-chloro-2-heptyne 

Downstream Products

• 1084795-48-1 C₁₅H₁₉BrO 
• 1294009-48-5 3-butyl-1,2-diphenyl-3-pyrroline 

Relevant articles and documents

Two-step allylic carbon insertion between ketone carbonyl and α carbons giving α-quaternary α-vinyl ketones

Ketones 1 were converted to α-quaternary α-vinyl ketones 2 by a two-step formal allylic carbon insertion between ketone carbonyl and α carbons, which involves the reaction of 1 with propargyltitanium reagents, derived from propargyl carbonates 3 and a divalent titanium reagent Ti(O-i-Pr)4/2i-PrMgCl, and the following rearrangement of the resulting α-allenyl alcohols 4 with NBS.