141474-37-5Relevant articles and documents
A Practical Procedure for Regioselective Bromination of Anilines
Takahashi, Yusuke,Seki, Masahiko
, p. 1828 - 1832 (2021/04/15)
A highly practical procedure for the preparation of bromoanilines by using copper-catalyzed oxidative bromination has been developed. Treatment of free anilines with readily available NaBr and Na 2S 2O 8in the presence of a catalytic amount of CuSO 4·5H 2O enabled regioselective bromination.
A kind of organic compound and its use this organic compound electroluminescent device
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Paragraph 0086-0089;0090, (2016/10/08)
The invention relates to an organic compound. The organic compound has a structure represented in a formula I, wherein R1, R2 and R3 are independently selected from hydrogen atom, substituted or non-substituted C1-C30 alkyl, substituted or non-substituted C1-C30 naphthenic base, substituted or non-substituted C1-C30 alkoxy, substituted or non-substituted C6-C30 aryl, substituted or non-substituted C6-C30 aryloxy, substituted or non-substituted C6-C30 arylamine, substituted or non-substituted C2-C30 heterocyclic ring, substituted or non-substituted C6-C30 condensed polycyclic group, hydroxyl, cyano group and substituted or non-substituted amino, respectively. Furthermore, the invention relates to an electroluminescent device, wherein the electroluminescent device comprises a hole injection layer and/or a hole transport layer using at least one of the compounds.
Polymer-supported organotin reagents for regioselective halogenation of aromatic amines
Chretien, Jean-Mathieu,Zammattio, Francoise,Le Grognec, Erwan,Paris, Michael,Cahingt, Blanche,Montavon, Gilles,Quintard, Jean-Paul
, p. 2870 - 2873 (2007/10/03)
(Chemical Equation Presented) Polymer-supported triorganotin halides were used in the halogenation reaction of aromatic amines. Treatment of aromatic amines with n-butyllithium and polymer-supported organotin halides gave the corresponding polymer-bound N-triorganostannylamines, which by treatment with bromine or iodine monochloride gave the para-halogenated aromatic amines with high yields and high selectivities. The polymer-supported organotin halides reagents regenerated during the course of the halogenation reaction can be reused without loss of efficiency. The presence of tin residues in halogenated aromatic amines was also investigated and evaluated at under 20 ppm after three runs.