141479-87-0Relevant articles and documents
pH-independent hydrolysis of 4-nitrophenyl 2,2-dichloropropionate in aqueous micellar solutions: Relative contributions of hydrophobic and electrostatic interactions
Seoud, Omar A. E.I.,Ruasse, Marie-Francoise,Possidonio, Shirley
, p. 526 - 532 (2001)
The pH-independent hydrolysis of 4-nitrophenyl 2,2-dichloropropionate (NPDCP) in the presence of aqueous micelles of sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, alkyltrimethylammonium chlorides, alkyldimethylbenzylammonium chlorides (alkyl = cetyl and dodecyl) and polyoxyethylene(9) nonylphenyl ether was studied spectrophotometrically. The observed rate constants, kobs, decrease in the following order: bulk water >cationic micelles >anionic micelles >non-ionic micelles. This order is different from that observed for pH-independent hydrolysis of 4-nitrophenyl chloroformate (NPCF), whose reaction is faster in cationic micelles than in bulk water. A proton NMR study on solubilization of a model ester, 4-nitrophenyl 2-chloropropionate, showed that the methylene groups in the middle of the surfactant hydrophobic chain are most affected by the solubilizate. Lower polarity and high ionic strength of interfacial water decrease the rates of hydrolysis of both NPCF and NPDCP, but t he fraction of the former ester that diffuses to the interface is probably higher than that of the latter. Therefore, whereas the (negatively charged) transition state of NPCF is stabilized by cationic interfaces and destabilized by anionic interfaces, that of NPDCP is negligibly affected by ionic interfaces, which explains the observed rate retardation by all ionic micelles. Calculated activation parameters corroborate our explanation.
Chiral Mesogenic Compounds: Carbocyclic and Heterocyclic Schiff Bases
Barbera, J.,Melendez, E.,Serrano, J. L.,Sierra, M. T.,Ezcurra, A.,Jubindo, M. A. Perez
, p. 151 - 158 (2007/10/02)
Five different chiral p-substituted anilines derived from 4-aminobenzoic acid and from 4-aminophenol were condensed with four carbocyclic and heterocyclic aldehydes in order to obtain chiral Schiff bases resembling DOBAMBC and HOBACPC.With the exception of the pyridine-3-carboxaldehyde derivatives, the compounds are mesomorphic.Some of the compounds exhibit ferroelectric SC* phases, and all exhibit SA or Ch mesophases on heating.Benzaldehyde and pyridine-2-carboxaldehyde derivatives show similar mesomorphic behavior, as was to be expected from MNDO semiempirical calculations.Values of the spontaneous polarization of certain compounds were measured.
