1414838-17-7Relevant articles and documents
Regio- and stereoselective olefination of phenol carbamates through C-H bond functionalization
Li, Bin,Ma, Jianfeng,Liang, Yujie,Wang, Nuancheng,Xu, Shansheng,Song, Haibin,Wang, Baiquan
supporting information, p. 1950 - 1962 (2013/05/09)
Two pathways that can be used to access ortho-olefinated phenol carbamate, including a ruthenium(II)-catalyzed oxidative olefination of phenol carbamate with acrylates and a rhodium(III)-catalyzed alkyne hydroarylation of phenol carbamate with internal alkynes through direct C-H activation, are reported. Both reactions afford substituted alkenes in a highly regio- and stereoselective manner. A highly regio- and stereoselective olefination of phenol carbamates through RuII-catalyzed oxidative olefination and Rh III-catalyzed alkyne hydroarylation are reported.
