1416249-12-1

Basic information

• Product Name: [lead(II)(2,3,5,6-tetraiodo-1,4-benzenedicarboxylate (+1H))2(dimethylsulfoxide)4]
• CAS NO: 1416249-12-1
• Molecular Weight: 1837
• Mol File: 1416249-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [lead(II)(2,3,5,6-tetraiodo-1,4-benzenedicarboxylate (+1H))2(dimethylsulfoxide)4](CAS DataBase Reference)
• NIST Chemistry Reference: [lead(II)(2,3,5,6-tetraiodo-1,4-benzenedicarboxylate (+1H))2(dimethylsulfoxide)4](1416249-12-1)
• EPA Substance Registry System: [lead(II)(2,3,5,6-tetraiodo-1,4-benzenedicarboxylate (+1H))2(dimethylsulfoxide)4](1416249-12-1)

Safety Data

• Hazardous Substances Data: 1416249-12-1(Hazardous Substances Data)

Upstream product

• 7606-84-0 tetraiodo-terephthalic acid 
• 68-12-2 N,N-dimethyl-formamide 

Relevant articles and documents

Syntheses, crystal structures, and properties of lead(II), zinc(II), and manganese(II) complexes constructed from 2, 3, 5, 6-tetraiodo-1, 4-benzenedicarboxylic acid

Three new coordination compounds, [Pb(HBDC-I4) 2(DMF)4](1) and [M(BDC-I4)(MeOH) 2(DMF)2]n (M = ZnII for 2 and MnII for (3) (H2BDC-I4 = 2, 3, 5, 6-tetraiodo-1, 4-benzenedicarboxylic acid), were synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis, and X-ray single crystal structure analysis. Single-crystal X-ray diffraction reveals that 1 crystallizes in the monoclinic space group C2/c and has a discrete mononuclear structure, which is further assembled to form a two-dimensional (2D) layer through intermolecular O-H···O and C-H···O hydrogen bonding interactions. The isostructural compounds 2 and 3 crystallize in the space group P21/c and have similar one-dimensional (1D) chain structures that are extended into three-dimensional (3D) supramolecular networks by interchain C-H···π interactions. The PbII and Zn II complexes 1 and 2 display similar emissions at 472 nm in the solid state, which essentially are intraligand transitions. Copyright