1416347-53-9

Basic information

• Product Name: 2,2'-methylenebis-[6-(1-methylcyclohexyl)-p-cresoylphthalonitrile]
• Synonyms: 2,2'-methylenebis-[6-(1-methylcyclohexyl)-p-cresoylphthalonitrile]
• CAS NO: 1416347-53-9
• Molecular Weight: 672.87
• Mol File: 1416347-53-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2'-methylenebis-[6-(1-methylcyclohexyl)-p-cresoylphthalonitrile](CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-methylenebis-[6-(1-methylcyclohexyl)-p-cresoylphthalonitrile](1416347-53-9)
• EPA Substance Registry System: 2,2'-methylenebis-[6-(1-methylcyclohexyl)-p-cresoylphthalonitrile](1416347-53-9)

Safety Data

• Hazardous Substances Data: 1416347-53-9(Hazardous Substances Data)

Upstream product

• 31643-49-9 4-Nitrophthalonitrile 
• 77-62-3 2,2'-methylenebis[6-(1-methylcyclohexyl)-p-cresol] 

Downstream Products

• 1416352-53-8 23,10,16,24-tetrakis(2,2'-methylenebis-[6-(1-methylcyclohexyl-5-methyl-phenoxy-phthalonitrile)]-p-cresoyl)phthalocyaninato Co(II) 
• 1416352-58-3 2',10',16',24'-tetrakis[2,2'-methylenebis-(6-(1-methylcyclohexyl-p-cresoyl)) ]phthalo-cyaninato Zn(II) 

Relevant articles and documents

Electrochemical and electrical properties of novel mono and ball-type phthalocyanines

New mononuclear Co(II) phthalocyanine 3 and ball-type homobinuclear Cu(II)-Cu(II) and Zn(II)-Zn(II) phthalocyanines, 4 and 5 respectively, were synthesized using the corresponding metal salts and the 4,4′-(methane-5- methyl-3-(1-methylcyclohexyl)-2,2′-phenoxy)diphthalonitrile ligand 2, which was prepared from the reaction of 4-nitrophthalonitrile with bis[2-hydroxy-5-methyl-3-(1-methylcyclohexyl)phenyl]methane (1). The novel compounds 3-5 have been characterized using their elemental analysis data and UV-Vis, IR, 1H NMR and MALDI-TOF mass spectra. The redox properties of the complexes were investigated by cyclic voltammetry in a non-aqueous medium. The electrochemical measurements showed that complex 5 forms a mixed-valence reduction species, due to the strong intramolecular interactions between the two phthalocyanine rings. Complex 4 displayed Pc ring-based redox signals with very high peak currents, which were attributed to the adsorption of the complex on the working electrode. Dc and ac electrical properties of films of 3, 4 and 5 were also investigated as a function of temperature (295-523 K) and frequency (40-105 Hz). From the dc conductivity measurements, activation energy values of the films were found, being 0.70, 0.66 and 0.68 eV for films of 3, 4 and 5, respectively. From impedance spectroscopy measurements, it was observed that the bulk resistance decreases with increasing temperature, indicating semiconductor properties.