1416465-79-6

Basic information

• Product Name: C₁₇H₂₄BrNO
• CAS NO: 1416465-79-6
• Molecular Weight: 338.288
• Mol File: 1416465-79-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₄BrNO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₄BrNO(1416465-79-6)
• EPA Substance Registry System: C₁₇H₂₄BrNO(1416465-79-6)

Safety Data

• Hazardous Substances Data: 1416465-79-6(Hazardous Substances Data)

Upstream product

• 1009-67-2 2-methyl-3-phenylpropionic acid 
• 89796-19-0 2-bromo-N-(tert-butyl)prop-2-en-1-amine 
• 38385-67-0 (2S)-2-Methyl-3-phenylpropanoic acid chloride 

Relevant articles and documents

Memory of chirality in rebound cyclizations of α-amide radicals

Reduction of (S)-N-(2-bromoallyl)-N-(tert-butyl)-2-methyl-3- phenylpropanamide with tributyltin hydride provides (3S,4S)-3-benzyl-1-(tert- butyl)-3,4-dimethylpyrrolidin-2-one with about 80% retention of chirality at the stereocenter adjacent to the amide carbonyl group. This memory of chirality is suggested to occur by transfer of chirality from a stereocenter to an axis, then from the axis back to a new stereocenter.