141666-30-0

Basic information

• Product Name: 2,4-Oxazolidinedione, 5-[(4-methylphenyl)methylene]-3-propyl-, (Z)-
• CAS NO: 141666-30-0
• Molecular Formula: C14H15NO3
• Molecular Weight: 245.278
• Mol File: 141666-30-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-Oxazolidinedione, 5-[(4-methylphenyl)methylene]-3-propyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Oxazolidinedione, 5-[(4-methylphenyl)methylene]-3-propyl-, (Z)-(141666-30-0)
• EPA Substance Registry System: 2,4-Oxazolidinedione, 5-[(4-methylphenyl)methylene]-3-propyl-, (Z)-(141666-30-0)

Safety Data

• Hazardous Substances Data: 141666-30-0(Hazardous Substances Data)

Upstream product

• 141666-50-4 3-propyl-oxazolidine-2,4-dione 
• 104-87-0 4-methyl-benzaldehyde 
• 141666-40-2 3-n-Propyl-4-(trimethylsiloxy)-5-(trimethylsilyl)-1,3-oxazolin-2-on 

Relevant articles and documents

Reactions of Trialkylsilyl Trifluoromethanesulfonates XI. - Synthesis of α-Oxocarboxylic Acid Derivatives from 2-O-Functionalized Trimethylsilyl Ketene Acetals

The cyclic ketene acetals 3, 5 are prepared from the dioxolanone 2 resp. the oxazolidinediones 4 by silylation with trimethylsilyl triflate (1)/triethylamine.In an aldol addition/Peterson olefination reaction catalysed by 1 the ketene acetals 3, 5 yield the (E/Z)-benzylidene derivatives 7, 12, 13 in reaction with aromatic aldehydes 6.In a side reaction the α-(trimethylsilyl)benzylidene derivatives 8 are formed from 3 and 6.Compounds 7 can be hydrolysed to yield α-ketocarboxylic acids 14.The latter are also obtained via β-elimination of trimethylsilanol from 2,3-bis(trimethylsiloxy)carboxylic acid anhydride/DMAP/pyridine. Key Words: 1,3-Dioxolanes / 1,3-Oxazolidines / α-Oxocarboxylic acids