1418143-59-5

Basic information

• Product Name: 1-bromo-2-cyclohexyl-3-buten-2-ol
• CAS NO: 1418143-59-5
• Molecular Weight: 233.148
• Mol File: 1418143-59-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-2-cyclohexyl-3-buten-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-2-cyclohexyl-3-buten-2-ol(1418143-59-5)
• EPA Substance Registry System: 1-bromo-2-cyclohexyl-3-buten-2-ol(1418143-59-5)

Safety Data

• Hazardous Substances Data: 1418143-59-5(Hazardous Substances Data)

Upstream product

• 823-76-7 Cyclohexyl methyl ketone 

Downstream Products

• 1418143-54-0 (2Z)-4-bromo-3-cyclohexyl-2-buten-1-yl acetate 

Relevant articles and documents

Mechanism and scope of the MnIII-initiated oxidation of β-ketocarbonyl compounds: Furan synthesis

Unless the MnIII-produced carbon-radical from β-ketocarbonyl compounds undergoes smooth intramolecular addition to alkenes, it traps molecular oxygen in the reaction medium to produce a peroxy radical, which reacts with the neighbouring carbonyl group to form 1,2-dioxetane. Thermal decomposition of 1,2-dioxetane completes the oxidation to produce α-oxo ester. This oxidation seems to be general at 50°C under aerobic conditions, and can be catalytic for MnIII in AcOH with ultrasonic irradiation. Thus, the development of a new synthetic method for diversely substituted furans has been accomplished based on a couple of the MnIII-initiated domino oxidation of β-ketocarbonyl compounds with a suitable α-allylic substitution. Copyright