14182-67-3

Basic information

• Product Name: 2-Butenoic acid, 2-methyl-4-phenyl-, ethyl ester, (E)-
• CAS NO: 14182-67-3
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 14182-67-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 2-methyl-4-phenyl-, ethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 2-methyl-4-phenyl-, ethyl ester, (E)-(14182-67-3)
• EPA Substance Registry System: 2-Butenoic acid, 2-methyl-4-phenyl-, ethyl ester, (E)-(14182-67-3)

Safety Data

• Hazardous Substances Data: 14182-67-3(Hazardous Substances Data)

Upstream product

• 6783-05-7 trans-2-phenylvinylboronic acid 
• 3699-66-9 ethyl 2-diethoxyphosphorylpropionate 
• 122-78-1 phenylacetaldehyde 
• 138344-84-0 (E)-ethyl 2-methyl-4-phenylbut-3-enoate 
• 90685-76-0 ethyl 2-nitro-2-methylbut-3-enoate 
• 591-51-5 phenyllithium 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 
• 4025-71-2 2-phenylethylsulfonyl chloride 
• 1297606-65-5 C₁₃H₁₇ClO₃ 

Downstream Products

• 1240239-86-4 C₁₇H₁₆INO 
• 138344-84-0 (E)-ethyl 2-methyl-4-phenylbut-3-enoate 
• 52497-56-0 (E)-2-methyl-4-phenyl-but-2-en-1-ol 

Relevant articles and documents

Regio- and Stereo-selective γ-Substitution of Allylic Nitro Compounds with Lithium Dialkylcuprates

Regio- and stereo-selective γ-substitution of allylic nitro compounds with lithium dialkylcuprates provides a new synthesis for trisubstituted olefins.

Olefination of carbonyl compounds through reductive coupling of alkenylboronic acids and tosylhydrazones

The partners decide: The C-C bond-forming reductive cross-coupling of alkenylboronic acids and tosylhydrazones takes place under mild reaction conditions without the need of a metal catalyst, thus giving rise to olefination-type products (see scheme). The position of the double bond in the product is determined by the structure of the coupling partners. Copyright

Domino carbopalladation-carbonylation: Generating quaternary stereocenters while controlling β-hydride elimination

A domino carbopalladation-carbonylation sequence for substrates possessing β-hydrogens is explored. This allows for the construction of complex architectures with vicinal stereocenters in a concise and rapid fashion via the stereocontrolled formation of two carbon-carbon bonds. An integral aspect of this domino reaction is the ability to control β-hydride elimination of the organopalladium intermediate and instead form the carbonylation product.