142024-88-2

Basic information

• Product Name: 3-Pentanone, 1-(acetyloxy)-2,2-dimethyl-1-phenyl-
• CAS NO: 142024-88-2
• Molecular Formula: C15H20O3
• Molecular Weight: 248.322
• Mol File: 142024-88-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 1-(acetyloxy)-2,2-dimethyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 1-(acetyloxy)-2,2-dimethyl-1-phenyl-(142024-88-2)
• EPA Substance Registry System: 3-Pentanone, 1-(acetyloxy)-2,2-dimethyl-1-phenyl-(142024-88-2)

Safety Data

• Hazardous Substances Data: 142024-88-2(Hazardous Substances Data)

Upstream product

• 221675-86-1 3-acetoxy-2,2-dimethyldihydrocinnamic acid 
• 52178-65-1 ethyl 3-hydroxy-2,2-dimethyl-3-phenylpropanoate 
• 23985-59-3 3-hydroxy-2,2-dimethyl-3-phenylpropanoic acid 
• 92115-30-5 2,2-dimethyl-1-phenylpentane-1,3-dione 
• 75-36-5 acetyl chloride 
• 999-75-7 ethylzinc iodide 

Downstream Products

• 565-69-5 ethyl isopropyl ketone 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Clemmensen Reduction. X. The Synthesis and Acidolysis of Some Aryl Alkyl Substituted Cyclopropane-1,2-diols

The synthesis of a number of 1-alkyl-2-arylcyclopropane-1,2-diols is reported.Reductive treatment of suitably substituted 1,3-diketones gave a cyclopropanediyl diacetate from which the diol was obtained.Reaction of these diols with acid gave α-hydroxy ketones, in which an alkyl group, rather than an aryl group, was adjacent to the carbonyl function.Clemmensen reduction of the 1,3-diketones gave products of rearrangement, generally similar to those obtained by acidolysis of the cyclopropane-1,2-diols.The relationship of these results to thermochemical studies on the stability of carboxonium ions is discussed.