142029-25-2

Basic information

• Product Name: (2-O-C₆H₄C(CH₃)NNHC₆H₅)2copper
• CAS NO: 142029-25-2
• Molecular Weight: 514.086
• Mol File: 142029-25-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-O-C₆H₄C(CH₃)NNHC₆H₅)2copper(CAS DataBase Reference)
• NIST Chemistry Reference: (2-O-C₆H₄C(CH₃)NNHC₆H₅)2copper(142029-25-2)
• EPA Substance Registry System: (2-O-C₆H₄C(CH₃)NNHC₆H₅)2copper(142029-25-2)

Safety Data

• Hazardous Substances Data: 142029-25-2(Hazardous Substances Data)

Upstream product

• 7327-78-8 o-hydroxyacetophenone phenylhydrazone 

Relevant articles and documents

Studies on the coordination of Cu(II) with o-hydroxyacetophenone-phenylhydrazones

Complexes of o-hydroxyacetophenone-phenylhydrazone (OHAPH) and its methyl and chloro drivatives with Cu(II) ion have been isolated.The complexes have been characterised on the basis of magnetic susceptibility and IR and ESR spectral measurements.ESR spectra reveal superhyperfine splitting, characteristic of the coordinated nitrogen of C=N bond.The bonding parameters α and β, though approximate, indicate in-plane and out-of-plane ?-bonding which stabilises the square-planar stereochemistry of the complexes.The solution stability constants of the metal chelates obtained from the potentiometric study provide supporting evidence for (i) intermolecular H-bonding between the phenolic oxygen and the nitrogen of the secondary amino group, and (ii) back donation from metal to ligand through ?-bonding.